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│ M A T E R I A L S A F E T Y
D A T A S H E E T │
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│ SECTION 1 - CHEMICAL PRODUCT AND
COMPANY IDENTIFICATION │
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MANUFACTURER: A.V.W. Inc
24 HOUR EMERGENCY PHONE NUMBER 800-424-9300 DATE PRINTED: 01/20/2012
PRODUCT NAME: Pro Stick 25 Textile Spray
Adhesive
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│ SECTION 2 - COMPOSITION/INFORMATION
ON INGREDIENTS │
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WT/WT %
ITEM
------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
───────────────────────────────────────────────────────────────────────────
01
HEXANE
110-54-3 35.0 %
02
ACETONE
67-64-1 20.0 %
03
ISOBUTANE 75-28-5 15.0 %
04
PROPANE
74-98-6 10.0 %
05
DIMETHYL ETHER 115-10-6 10.0 %
---------------------- EXPOSURE LIMITS
--------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA
SKIN
───────────────────────────────────────────────────────────────────────────
01 50 ppm N.E. 500 ppm N.E. N.E. NO
02 500 ppm 750 ppm 1000 ppm N.E. N.E. NO
03
N.E. N.E. N.E. N.E. 1000 ppm NO
04 2500 PPM
N.E. 1000 ppm N.E. N.E. NO
05
N.E. N.E. N.E. N.E. 1000 ppm NO
(See Section 16 for abbreviation legend)
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│ SECTION 3 - HAZARDS
IDENTIFICATION │
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*** EMERGENCY OVERVIEW ***: Keep from reach of children. Do not puncture,
incinerate, or
place aerosol product containers in compactors.
Containers
of this material
may be hazardous when emptied since containers retain
product residues
(vapor, liquid, and/or solid). All
hazard precautions
given must be
observed. Do not flame cut, braze or use welding
torch.
Intentional misuse by deliberately
concentrating and inhaling this product
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Page 2
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│ SECTION 3 - HAZARDS
IDENTIFICATION │
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may be harmful or
fatal.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Can cause severe irritation,
redness, tearing,
blurred vision.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact can
cause moderate
irritation defatting, dermatitis.
EFFECTS OF OVEREXPOSURE - INHALATION: Excessive inhalation of vapors can
cause nasal and
respiratory irritation, dizziness, weakness, fatigue,
nausea, headache,
possible unconsciousness, and even asphyxiation.
Overexposure may cause damage to the nervous
system.
EFFECTS OF OVEREXPOSURE - INGESTION: No Information.
EFFECTS OF OVEREXPOSURE - CHRONIC
HAZARDS: Overexposure to this
material
(or its components)
has apparently been found to cause the following
effects in
laboratory animals: kidney damage, eye damage,
liver damage,
lung damage, nasal damage,
nervous system damage, testis
damage,
Overexposure to this material (or its
components) has apparently been found
to cause the
following effects in humans: visual
impairment, central
nervous system
effects,
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION
EYE
CONTACT
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│ SECTION 4 - FIRST AID
MEASURES │
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FIRST AID - EYE CONTACT: Flush with large amounts of water, lifting
upper
and lower lids
occasionally, get medical attention.
FIRST AID - SKIN CONTACT: Thoroughly wash exposed area with soap
and
water. Remove contaminated clothing. Launder contaminated clothing before
re-use. Get medical attention if irritation
persists. Mineral oil, baby
oil, makeup
remover, mineral spirits, or other similar mild solvent may be
used to remove the
sticky resin residue left by the adhesive.
FIRST AID - INHALATION: Remove individual to fresh air. If breathing is
difficult,
administer oxygen. Give artificial
respiration if breathing has
stopped. Keep person warm and quiet. Get medical attention.
FIRST AID - INGESTION: Do not induce vomiting. Give two glasses of water
if conscious. Never give anything by mouth to an
unconscious person. Get
immediate medical
attention.
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│ SECTION 5 - FIRE FIGHTING
MEASURES │
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FLASH POINT: -156 F LOWER EXPLOSIVE
LIMIT: 1.0 %
(PENSKY-MARTENS C.C.) UPPER EXPLOSIVE
LIMIT: 18.0 %
(Continued on Page 3)
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Page 3
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│ SECTION 5 - FIRE FIGHTING
MEASURES │
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AUTOIGNITION TEMPERATURE: N.D.
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM
WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are heavier than air and travel
along the ground or
may be moved by ventilation and ignited by ignition
sources at
locations distant from material handling point.
For aerosol
products - exposure
to temperatures over 130F may cause containers to burst
releasing highly
flammable gas.
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus
with a full facepiece operated in pressure-demand or other
positive
pressure mode when
fighting fires. Keep fire exposed
containers cool with
water fog.
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│ SECTION 6 - ACCIDENTAL RELEASE
MEASURES │
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STEPS TO BE TAKEN IN CASE MATERIAL IS
RELEASED OR SPILLED: Eliminate
sources of ignition
& ventilate area. Persons not properly
equipped should
be excluded from
area. Stop spill at source - prevent
spreading. Avoid
inhalation of
vapors. Avoid skin contact with
liquid. Soak up on
absorbent material
and place into proper container for disposal.
Use
non-sparking scoops
for flammable materials. Clean walking
surfaces
thoroughly to
reduce slipping hazard.
┌─────────────────────────────────────────────────────────────────────────┐
│ SECTION 7 - HANDLING AND
STORAGE │
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HANDLING:
Containers of this material may be hazardous when emptied, since
containers retain
product residues (vapor, liquid, and/or solid).
All
hazard precautions
given must be observed. Do not flame
cut, braze or use
welding torch on
containers. Intentional misuse by
deliberately
concentrating and
inhaling the vapors from this product may be harmful or
fatal.
STORAGE:
Do not store above 120F. Do not
store in direct sunlight. Keep
away from heat
sources, open flame, pilot lights, sparks, and other sources
of ignition. Do not store above 120F. Do not store in direct sunlight.
┌─────────────────────────────────────────────────────────────────────────┐
│ SECTION 8 - EXPOSURE
CONTROLS/PERSONAL PROTECTION
│
└─────────────────────────────────────────────────────────────────────────┘
ENGINEERING CONTROLS: Provide sufficient mechanical ventilation
(general
and/or local
exhaust) ventilation to maintain exposure below TLV(s).
RESPIRATORY PROTECTION: If work place exposure limits of product or
any
component is
exceeded, use a NIOSH/MSHA approved respirator.
Consult your
safety equipment
supplier for recommendations.
SKIN PROTECTION: Wear impervious gloves if method of use
involves skin
(Continued on Page 4)
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Page 4
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│ SECTION 8 - EXPOSURE CONTROLS/PERSONAL
PROTECTION │
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contact with
product. Consult your safety supply
vendor for glove
recommendations.
EYE PROTECTION: Wear safety glasses at minimum, more
extensive protection
may be necessary
depending on how the product is to be used.
OTHER PROTECTIVE EQUIPMENT: Wear impervious clothing if bodily exposure
is
anticipated. Consult your safety supply vendor for
recommendations.
HYGIENIC PRACTICES:
designated areas
only. Remove and launder clothing if
contaminated.
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│ SECTION 9 - PHYSICAL AND CHEMICAL
PROPERTIES │
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BOILING RANGE :
-44 - 159 F VAPOR DENSITY : Is heavier than air
ODOR : MINT WHEN WET ODOR THRESHOLD : N.D.
APPEARANCE : WHITE LIQUID EVAPORATION RATE: Is faster than Butyl
SOLUBILITY IN H2O :
NEGLIGIBLE Acetate
FREEZE POINT : N.D. SPECIFIC GRAVITY: 0.7232
VAPOR PRESSURE : N.D. pH @ 0.0
% : N.D.
COEFFICIENT OF WATER/OIL DISTRIBUTION:
N.D.
(See Section 16 for abbreviation legend)
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│ SECTION 10 - STABILITY AND
REACTIVITY │
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CONDITIONS TO AVOID: Heat, sparks, welding arcs, open flame, pilot
lights,
static electricity
or other source of ignition.
INCOMPATIBILITY: oxidizing agents, acids,
reducing agents, strong
oxidizers,
HAZARDOUS DECOMPOSITION PRODUCTS: carbon monoxide and carbon dioxide,
various
hydrocarbons, sulfur dioxide, sulfur monoxide,
HAZARDOUS POLYMERIZATION: Will not occur
under normal conditions.
STABILITY: This product is stable under
normal storage conditions.
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│ SECTION 11 - TOXICOLOGICAL PROPERTIES │
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No product or component toxicological
information is available.
(Continued on Page 5)
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Page 5
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│ SECTION 12 - ECOLOGICAL INFORMATION │
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ECOLOGICAL INFORMATION: No Information.
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│ SECTION 13 - DISPOSAL
CONSIDERATIONS │
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DISPOSAL METHOD: Dispose of in accordance with all local,
state and
federal
regulations.
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│ SECTION 14 - TRANSPORTATION
INFORMATION │
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DOT PROPER SHIPPING NAME: Aerosols
DOT TECHNICAL NAME:
DOT HAZARD CLASS: 2.1 HAZARD SUBCLASS: NONE
DOT UN/NA NUMBER: UN1950 PACKING GROUP: NONE RESP. GUIDE PAGE: 126
ADDITIONAL INFORMATION:: For domestic ground and air shipment
this product
may be shipped as a
Consumer Commodity ORM-D. Outer cartons
must have the
ORM-D or ORM-D AIR
designation. (our original cartons are
preprinted with
the ORM-D
designation for ground shipment)
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│ SECTION 15 - REGULATORY
INFORMATION │
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OSHA: Hazardous by definition of Hazard Communication
Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to
the EPA 'Hazard Categories'
promulgated under
Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III)
and is considered, under
applicable
definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
PRESSURIZED
GAS HAZARD
SARA SECTION 313:
This product contains the following
substances subject to the reporting
requirements of
Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER
WT/WT % IS LESS THAN
HEXANE
110-54-3 35.0 %
TOXIC SUBSTANCES CONTROL ACT:
(Continued on Page 6)
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│ SECTION 15 - REGULATORY
INFORMATION │
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TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical
substances subject to the
reporting
requirements of TSCA 12(B) if exported from the
----------- CHEMICAL NAME ----------- CAS NUMBER
No information is available.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared
in compliance with Controlled
Product Regulations except
for use of the 16 headings.
CANADIAN WHMIS CLASS: No information
available.
: Hexane
is a mixture of n-hexane and other compounds all falling under
the general
chemical name light hydrotreated distillate
CAS-68410-97-9.
The n-hexane content of our hexane is 60 to
70 percent. On June 30, 1993
the OSHA Z-1-A
table was revoked and OSHA reverted back to their prior
exposure
limits. The values on this MSDS reflect
the roll back to the
prior values. Some states may continue to enforce the 1993
limits. On
June 16, 1995 EPA announced in a final rule
that acetone would no longer be
considered a VOC
for air attainment standards.(it is now an exempt
compound) The VOC calculations on this MSDS are based
on acetone being an
exempt
compound. The June 16 rule also removed
acetone from the list of
SARA 313 reportable
chemicals.
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│ SECTION 16 - OTHER
INFORMATION │
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HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 4 REACTIVITY: 1
PREVIOUS MSDS REVISION DATE: 02/24/03
REASON FOR REVISION: NEW LOW VOC
FORMULA
VOC CONTENT:
63.9 % BY WEIGHT, 444 GRAMS/LITER TOTAL PRODUCT,
515 GRAMS/LITER LESS WATER AND
EXEMPT, 0.45 LBS/CAN
LEGEND:
N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
:
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